Polythioamides
WebThrough the design of a pyridine-activated diyne monomer, the catalyst-free multicomponent polymerizations of sulfur, aromatic alkyne, and a group of commercially available primary and secondary diamines were realized at room temperature or 40 °C, affording functional polythioamides with well-defined structures, high yields (up to 98%), high molecular … WebDec 22, 2024 · The production of elemental sulfur from petroleum refining has created a technological opportunity to increase the valorization of elemental sulfur by the synthesis of high-performance sulfur-based plastics with improved optical, electrochemical, and mechanical properties aimed at applications in thermal imaging, energy storage, self …
Polythioamides
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WebSulfur-containing polymers have been widely studied because of their high refractivity and low dispersion, but the efficient synthetic approach of them is quite limited. In this work, … WebFeb 8, 2024 · Through the design of a pyridine-activated diyne monomer, the catalyst-free multicomponent polymerizations of sulfur, aromatic alkyne, and a group of commercially available primary and secondary diamines were realized at room temperature or 40 °C, affording functional polythioamides with well-defined structures, high yields (up to 98%), …
WebFeb 18, 2013 · Polythioamides were synthesized by the Willgerodt-Kindler polycondensation reaction using dialdehydes, 4,4′-trimethylenedipiperidine, and sulfur. WebOct 1, 1990 · Functional Hyperbranched Polythioamides Synthesized from Catalyst‐free Multicomponent Polymerization of Elemental Sulfur †. Chinese Journal of Chemistry …
WebMar 8, 2024 · By using in-situ synthesis of polythioamide (PTA) on activated carbon (AC), a polythioamide-modified activated carbon-based adsorbent (AC-PTA) was successfully prepared and used to study the selective adsorption effect and mechanism of Au(Ⅲ) in wastewater. The results showed that AC-PTA exhibited ex … WebSulfur-containing polymers have renewed widespread attention due to their fascinating properties like high refractive index and semiconducting character. However, examples of …
WebThe aim of the present study was to design and synthesis a novel monomer to produce polyurethanes with improved thermal stability as well as good solubility. Herein, N1,N3-bis(5-hydroxynaphthalene-...
WebOct 22, 2015 · The polyamides and polythioamides were actually synthesized and characterized in terms of solubility, molecular weight, crystallinity, thermal transition, and … how to shorten a skagen watch bandWebThe two polythioamides were synthesized via the Willgerodt–Kinder type reaction according to Kanbara et al. 13 In Fig. 7, solution 13 C NMR spectra of PTA2T and PTA3T are compared with those of the model compounds, and the observed peaks are assigned as indicated. how to shorten a shoulder seamWebJan 1, 1980 · Polythioamides (n.6) have cyclized chain-ends arising from reaction between an amino-group and the conjugated dithioester formed via the base-catalysed cyclization of tetrathioadipates. The importance of this secondary reaction can be reduced by low temperature operation, using a slight excess of dithioester over amine ( ca. 5%) and a … nottingham family days outWebDec 16, 2024 · These polythioamides can be applied in gold recovery, which could extract a trace amount of Au 3+ from practical acidic leaching solution of discarded electronic … how to shorten a ski poleWebPreparation of other polythioamides was carried out analogously. Preparation of Model Compound Model compound of PTA-1, 1,19-bis(benzthioyl)-4,49-tri-methylenedipiperidine … nottingham fancy dress shopWebNov 1, 2001 · Willgerodt-Kindler type reactions of dialdehydes and diamines in the presence of sulfur were investigated for preparation of polythioamides. The one-pot, three … nottingham fc soccerwayhow to shorten a shower curtain liner